Tannic Acid-Enhanced Cellulose/PEDOT:PSS Films Exhibiting Low Electrical Hysteresis, UV Blocking, and Antibacterial Properties for Wearable Sensing

Ductile appearance, remarkable length-diameter ratio, flexible fabrication properties and featured additional functions of functional composite fibers elicit great interest in applications. In this paper, chitosan/poly(vinyl alcohol) composite fibers with different graphene oxide additive (1-7 wt.%) were spun via continuous wet-spinning route and the resultant fibers revealed improved thermal, UV blocking and dye absorptive properties. In details, the component of fibers was characterized by SEM, TEM, FTIR, XRD and the results indicated that the graphene oxide dispersed well in chitosan/PVA matrix and the hydrogen bond was occurred between these components. As expected, the highest graphene oxide content case (7 wt.% GO) possessed the extraordinary UV blocking property as its UPF value reached to 500 arising from UPF=8.11 of 0 wt.% GO case. However, the composite fiber with 1 wt.% GO, rather than 7 wt.% GO, expressed the remarkable thermal stability and dye absorptive property, and the dye absorptive property of 1 wt.% GO showed the highest absorptive capacity of 407 mg/g among all the resultant fibers.

Incorporating tannin onto regenerated cellulose film towards sustainable active packaging

Improving barrier and antibacterial properties of chitosan composite films by incorporating lignin nanoparticles and acylated soy protein isolate nanogel

This work reports the preparation of nano lignin-rich fraction material via green technology from the holistic use of lignocellulosic biomass bamboo. The bamboo is first chemically treated, followed by acid precipitation to extract bamboo-derived macro lignin-rich fraction material. The nano lignin-rich fraction material was then prepared via ultrasonication technique from the extracted bamboo-derived macro lignin-rich fraction material. The confirmation of the distinct lignin functional groups in the extracted lignin-rich fractions has been done by FTIR. Surface morphology by FESEM and TEM revealed spherical nano-lignin-rich fraction materials from extracted bamboo-derived macro lignin-rich fraction materials. DPPH assays indicated that both the obtained fractions depict beneficial antioxidant characteristics. They were found to be effective in terms of their antibacterial activity against both gram-positive bacteria Staphylococcus aureus (S.aureus) and gram-negative bacteria Escherichia coli (E.coli), using the disc diffusion method. These fractions have UV blocking property, and nano-lignin-rich fraction material acts as a more potential UV blocking agent than others. Thus, the nano-lignin-rich fraction material has great potential as a high antioxidant, antibacterial, and UV blocking agent useful in biomedical applications. Highlights Extraction of macro-lignin rich fraction material using chemical treatment of lignocellulosic biomass bamboo via refluxing followed by acid precipitation. Preparation of nano-lignin rich fraction material from extracted bamboo-derived macro-lignin rich fraction material via ultrasonication technique as a green technology. Structural and surface morphology of the extracted macro-lignin & nano lignin-rich fraction materials have been analyzed by XRD, FTIR, EDX, SEM and TEM. The macro lignin & nano lignin-rich fraction materials showed good antioxidant, antibacterial activity and UV-blocking properties, but the nano-lignin rich fraction material exhibited more efficient properties.

Antimicrobial and UV Blocking Properties of Composite Chitosan Films with Curcumin Grafted Cellulose Nanofiber

Lignin nanorods reinforced nanocomposite hydrogels with UV-shielding, anti-freezing and anti-drying applications

A facile method to fabricate UV blocking superhydrophobic cotton fabric based on the deposition of TiO2 sol followed by surface modification with stearic acid is presented here. TiO2 and STA-TiO2 coated cotton fabrics were characterised by scanning electron microscopy, X-ray diffraction studies and X-ray photoelectron spectroscopy. The UV transmittance spectral studies showed that the STA-TiO2 coated cotton had excellent UV blocking property in both UV-A and UV-B regions and in fact the hydrophobicity did not affect the UV blocking property of TiO2 coated cotton. Moreover, the STA-TiO2 coated cotton fabric had outstanding self-cleaning property which can be effectively used for oil-water separation studies. Further, the modified cotton exhibited excellent chemical durability and mechanical stability. Hence, this work can be exploited for industrial applications for the fabrication of textiles with superhydrophobic, UV blocking and self-cleaning characteristics.

New nanocomposite materials with UV-NIR blocking properties and hues ranging from green to brown were prepared by integrating inorganic tantalum octahedral cluster building blocks prepared via solid-state chemistry in a PMMA matrix. After the synthesis by the solid-state chemical reaction of the K4[{Ta6Bri12}Bra6] ternary halide, built-up from [{Ta6Bri12}Bra6]4- anionic building blocks, and potassium cations, the potassium cations were replaced by functional organic cations (Kat+) bearing a methacrylate function. The resulting intermediate, (Kat)2[{Ta6Bri12}Bra6], was then incorporated homogeneously by copolymerization with MMA into transparent PMMA matrices to form a brown transparent hybrid composite Ta@PMMAbrown. The color of the composites was tuned by controlling the charge and consequently the oxidation state of the cluster building block. Ta@PMMAgreen was obtained through the two-electron reduction of the [{Ta6Bri12}Bra6]2- building blocks from Ta@PMMAbrown in solution. Indeed, the control of the oxidation state of the Ta6 cluster inorganic building blocks occurred inside the copolymer, which not only allowed the tuning of the optical properties of the composite in the visible region but also allowed the tuning of its UV and NIR blocking properties.

Cellulose nanofiber-based multifunctional films integrated with carbon dots and anthocyanins from Brassica oleracea for active and intelligent food packaging applications

In this study, we evaluated the UV transmittance of spectacle lenses in the Turkish market, which are reported to have UV blocking properties, and tested their suitability. Samples were obtained from patients who were admitted to the ophthalmology outpatient clinic of our hospital for refractive error and who wore glasses as UV block. No limitation was made regarding the spectacle size and duration of spectacle wear. Measurements were tested by the principal investigator using an ultraviolet detector. The right and left lens were measured separately. All measurements were performed at room temperature (22-25°C) in a humidity regulated (20-40%) room without direct light. UV protection level was measured for 120 spectacles used for refractive errors. Only 28 (23.3%) of 120 glasses had protection level up to 400 nm UV. Twenty-four (20%) of the glasses had a protection level of 0 even though they were labeled as having UV blocking properties. It is clear that strict regulations need to be implemented to improve the protection levels of glasses.

Waste cotton clothes, including post-consumer denim fabrics, are abundant biopolymer sources due to their high cellulose content. These waste materials commonly end up in landfills, posing health and environmental concerns and losing valuable cellulosic materials. To address these, this study aims to extract and characterize microcrystalline cellulose (MCC) from post-consumer indigo denim fabrics using a one-step hydrothermal method and evaluate its UV-blocking properties. FTIR and TGA analysis of raw and bleached denim confirmed the presence and purity of cotton cellulose and the indigo dye. Extracted MCC yielded 70-84%, with a degree of polymerization (DP) of 281-299. XRD analysis of the MCC showed a cellulose Type I structure. FTIR suggests the removal of amorphous phases of cellulose, leaving the crystalline structure. SEM meanwhile revealed rod-shaped and rough-surfaced MCC particles with diameters of 10-20 μm and lengths of 45-60 μm. Both FTIR and SEM indicated the retention of indigo dye on MCC surface. Increased acid hydrolysis time led to smaller particle sizes and higher degree of crystallinity (CrI). Indigo PVA-MCC films showed good transparency and effective UV blocking. These results indicate the successful conversion of denim to MCC via the hydrothermal method and the stability of indigo dye in the cellulose matrix.

【This study analyzes how well-being lifestyle and functional textile knowledge effect the perception of high functional sports/leisure wear importance. A survey was conducted among male and female sports/leisure wear consumers aged 15 and over in the Daegu and Gyeongbuk area from May $12^{th}$ to June $2^{nd}$ 2009. A total of 288 responses were analyzed using descriptive statistics, factor analysis, and regression. As a result, 9 factors were determined as sub-elements of a well-being lifestyle. Knowledge levels for functional textiles were high in elastic, UV blocking, air permeable, and antibacterial properties. The perception of high functional sports/leisure wear importance was positively influenced by functional textile knowledge and two well-being lifestyle constructing factors ('self-confidence/affirmative thinking' and 'health/environment oriented eating habits').】

Microbial production of coconut fiber nanolignin for application onto cotton and linen fabrics to impart multifunctional properties

Poly (butylene adipate-co-terephthalate)/titanium dioxide/silver composite biofilms for food packaging application

Enhanced antibacterial properties of poly(butylene succinate-co-terephthalate)/Ag@MgO nanocomposite films for food packaging