Abstract

Ring auf, Ring zu: Eine bromkatalysierte Tandemsequenz aus Ringöffnung und Cyclisierung von bicyclischen Vinylcyclopropanen mit Chloramin-T ([TsNCl]Na) liefert chirale bicyclische Amidinderivate in guten Ausbeuten. Auf Grundlage der experimentellen Beobachtungen wird ein plausibler Mechanismus vorgeschlagen. Ts=p-Toluolsulfonyl.

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