Tailoring the morphology and charge transfer pathways of ultrathin Cd0.8Zn0.2S nanosheets via ionic liquid-modified Ti3C2 MXenes towards remarkable photocatalytic hydrogen evolution

Abstract

Small-sized CdxZn1–xS solid solution nanomaterial is an important candidate for efficient photocatalytic hydrogen evolution (PHE), but it still suffers from easy agglomeration, severe photo corrosion, and fast photogenerated electron-hole recombination. To tackle these issues, herein, we propose a new strategy to modify CdxZn1–xS nanoreactors by the simultaneous utilization of ionic-liquid)-assisted morphology engineering and MXene-incorporating method. That is, we designed and synthesized a novel hierarchical Cd0.8Zn0.2S/Ti3C2 Schottky junction composite through the in-situ deposition of ultrathin Cd0.8Zn0.2S nanosheets on unique IL-modified Ti3C2 MXenes by a one-pot solvothermal method for efficiently PHE. The unique construction strategy tailors the thickness of ultrathin Cd0.8Zn0.2S nanosheets and prevents them from stacking and agglomeration, and especially, optimizes their charge transfer pathways during the photocatalytic process. Compared with pristine Cd0.8Zn0.2S nanosheets, Cd0.8Zn0.2S/Ti3C2 has abundant photogenerated electrons available on the Ti3C2 surface for proton reduction reaction, owing to the absence of deep-trapped electrons, suppression of electron-hole recombination in Cd0.8Zn0.2S and high-efficiency charge separation at the Cd0.8Zn0.2S/Ti3C2 Schottky junction interface. Moreover, the hydrophilicity, electrical conductivity, visible-light absorption capacity, and surficial hydrogen desorption of Cd0.8Zn0.2S/Ti3C2 heterostructure are significantly improved. As a result, the heterostructure exhibits outstanding photocatalytic stability and super high apparent quantum efficiency, being rendered as one of the best noble-metal-free Cd-Zn-S-based photocatalysts. This work illustrates the mechanisms of morphology control and heterojunction construction in controlling the catalytic behavior of photocatalysts and highlights the great potential of the IL-assisted route in the synthesis of high-performance MXene-based heterostructures for photocatalytic hydrogen evolution.