Abstract
The role of the 2,2'-bipyridine ligand in metal to ligand charge transfer (MLCT) excited states and of the effect of substituent changes on that role has been investigated by spectroscopic and photochemical measurements on the series ((tpm)Ru(4,4'-(X){sub 2}-2,2'-bipyridine)(py)){sup 2+} (X = C(O)OC{sub 2}H{sub 5}, C{sub 6}H{sub 5}, CH{sub 3}, NH{sub 2}, H; tpm is tris(1-pyrazolyl)methane). 65 refs., 8 figs., 4 tabs.
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