Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene

Abstract

Two new fullerene–fluorene dyads, N-methyl-2-(2-fluorenyl)-3,4-[60]fuller-pyrrolydine ( 1) and N-methyl-2-(2-fluorenyl)-3,4-[70]fullerpyrrolydine ( 2), were synthesized and their structures were confirmed by MALDI-MS, 1H NMR and FT-IR. Their electrochemical and optical properties were investigated by cyclic voltammetry and Z-scan technique, including, electronic potentials, two-photon absorption cross-sections ( σ 2), nonlinear refractive indexes ( n 2), microscopic second-order hyperpolarizabilities ( γ R ) and third-order nonlinear susceptibilities ( χ I ( 3 ) and χ R ( 3 ) ). Importantly, the χ I ( 3 ) and σ 2 in 2 were increased above 35% due to [70]fullerene unit than that of 1.