Abstract
1. Treatment of chloropicolinic acids with aqueous solutions of various copper salts in alcohol media results in the formation of complexes of composition 2∶1. 2. The structures of the newly synthesized complexes have been shown to be identical in the solid state and in solution. 3. Diverse modes of coordination of picolinic acid derivatives have been demonstrated; this may be one of the factors responsible for the ease of formation of metallocomplexes in biological systems, and thus may be responsible for the high biological activity (of picolinic acid derivatives).
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