Abstract
The reaction of Mo(NN)(CO) 4 (NN = bipyridine, phenathroline) with CH 3OOCCCCOOCH 3 (DMAC) gives Mo(NN)(CO) 4(DMAC) 2. An X-ray diffraction study of the product (NN = bipyridine) indicates that the two CO groups are cis to each other, while the two DMAC ligands are in trans arrangement, and are mutually perpendicular with each DMAC eclipsing and NMoCO vector. In solution, the DMAC ligands appear to rotate about the MoDMAC bond as shown by the fluxional behavior in the NMR spectra of the products.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
