Abstract
Three organotin(IV) complexes with dithiomorpholincarbamate ligand: SnBr 2[S 2CN(CH 2CH 2) 2O] 2 ( 1), (4- F-C 6H 4CH 2) 2Sn(Cl)S 2CN(CH 2CH 2) 2O ( 2) and (2- F-C 6H 4CH 2) 3SnS 2CN(CH 2CH 2) 2O ( 3) have been synthesized and characterized by elemental analysis, IR, UV and NMR. Their crystal and molecular structures have been determined by X-ray single crystal diffraction. In the complex 1, the tin atom is rendered six-coordination in a distorted octahedron configuration. And in the complexes 2 and 3, the tin atoms are rendered five-coordination in a distorted trigonal bipyramidal structure.
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