Abstract
The synthesis of cycloalkyl-fused porphodimethenes from a mixture of products was investigated. Each product was separated via silica gel column chromatography and characterized using nuclear magnetic resonance (NMR) and UV-visible absorption spectroscopies, and mass spectrometry. X-ray crystal structure analysis revealed their gable-like bent conformations bearing perpendicular cycloalkyl rings in which the dipyrrin pairs contacted closely so that the neighboring pyrrole rings formed circular hydrogen bonding networks, such as those in porphyrins. Such configurations also caused extreme downfield shifts of the methylene protons of the cycloalkyl rings in the 1H NMR spectra.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
