Abstract

Two novel diazadioxaacene derivatives (ADOP and ADOQ) have been successfully synthesized and characterized. Their single crystal analyses disclose that molecule ADOP forms a twisted topology configuration, whereas ADOQ adopts reclining-chair architecture. Both of them emit strong blue fluorescence in organic solvents. Moreover, they can self-assemble to form regular nanobelts and nanowires, respectively, via a simple surfactant-assisted method.

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