Synthesis, optical properties and crystal structures of carbazole end-capped phenylene ethynylene blue light-emitting materials

Abstract

A class of highly fluorescent and stable carbazole end-capped phenylene ethynylene compounds have been synthesized and characterized. They show high extinction coefficients of absorption ( λ max abs = 33 0 – 34 0 nm ) and quantum yields of fluorescence ( λ max em = 393 – 396 nm ; Φ F=0.52–0.73) in dichloromethane. The solid state absorptions and emissions are significantly red-shifted from the dilute solution ones ( λ max abs = 358 – 375 nm ; λ max em = 396 – 458 nm ). Their photoluminescent properties and crystal structures have been investigated with the aim of providing a basis for elucidating the structure–physical property relationships. These data indicate their potential use as blue-emitting materials in organic light-emitting diodes (OLEDs).