Abstract
Unlike the reduction of [Ga-2,6-Trip2C6H3]Cl2 with sodium which produces the controversial “gallyne” Na2[(Ga-2,6-Trip2C6H3)2], reduction with potassium gives K2[Ga4(2,6-Trip2C6H3)2] (see structure). This suggests that the alkali metal countercations play an important role in stabilizing these species. Trip=2,4,6-iPr3C6H2.
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