Abstract

The decoration of bishydrazone compounds of types 2 and 3 by attachment of various side chains, in particular of biological nature, yields a set of functionalised ligands. Their self-assembly with zinc(II) and cobalt(II) ions into [2×2] grids provides an approach towards nanosized metallosupramolecular architectures presenting quartet receptor arrays of interest for the development of nanosized biochips.

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