Abstract
Abstract Pyridine-tetrafluoro-λ6-sulfanyl-alkynes have emerged as building blocks for synthesizing linearly-linked pyridine-heterocycles. They are prepared via a two-step procedure comprising the radical addition of pyridine-tetrafluoro-λ6-sulfanyl-chlorides and alkynes and subsequent base-promoted elimination of HCl. Herein we developed a straightforward alternative synthesis via the radical coupling of pyridine-tetrafluoro-λ6-sulfanyl-chlorides with ethynylbenziodoxolone reagents under LED irradiation.
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