Abstract

A procedure for the solution polymerization of styrene using di-tert-butyl peroxide (DTBP) as the initiator is described. The use of DTBP allows for end-group analysis by 1H NMR spectroscopy and calculation of the number-average molecular weight of the polymer. This experiment was designed as a laboratory introduction to polymer chemistry for second-year undergraduate students. The highest-order focus was to get students to derive an equation to calculate the number-average molecular weight by 1H NMR spectral analysis.

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