Abstract

A streamlined Pd-catalyzed direct oxidative arylation of the pentafluorobenzene C–H bond with readily available (diacetoxyiodo)arenes has been described. Under the optimized conditions, three (diacetoxyiodo)arene derivatives were found to undergo coupling with pentafluorobenzene to furnish the substituted (pentafluorophenyl)benzenes in moderate to good yields.

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