Abstract
A study of the reaction kinetics between the trinuclear palladium(II) acetate Pd 3(μ-OOCMe) 6 ( 1) and the mononuclear 3d-metal (Ni II, Co II, Cu II) acetates in acetic acid under water-specified conditions revealed a fairly complicated reaction mechanism triggered by the primary hydrolytic cleavage of an acetate bridge in molecule 1. The isolated reaction products, as established by X-ray diffraction study, are 1D polymeric complexes {Pd(μ-OOCMe) 4M(OH 2)(HOOCMe) 2} n (M = Ni II, Co II, Cu II, Mn II, Zn II) built of the Pd II-based paddlewheel units [Pd(μ-OOCMe) 4M] and linked trough the H-bonded H 2O and MeCOOH molecules.
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