Abstract
We report oxygenated cage compounds by acetalization and ring-closing metathesis (RCM) as key steps. We used ketalization and transannular cyclization to design octacyclic triooxygenated cage compounds. In previous studies, oxepane systems have been prepared using a three-step process via Grignard addition and RCM. The present strategy described here delivers the cage bisoxepane system in two steps via ketalization process. The bisoxepane and other derivatives are confirmed by single-crystal XRD studies.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
