Synthesis of novel ZSM-22 zeolite from Taiwanese coal fly ash for the selective separation of Rhodamine 6G

Abstract

The present study reveals the potential of coal fly ash (CFA) as the environmental pollutant adsorbent. The conventional approach of alkali fusion followed by hydrothermal treatment of Taiwan based coal fly ash resulted in new and novel zeolite material ZSM-22. The composition, morphology, chemical structure, and the surface properties of as-prepared zeolite were investigated using BET, SEM, FT-IR, XRD, and XRF. The specific surface area (SSA) of the zeolite is enhanced from 1.28 m2/g to 30.21 m2/g with a drop in Si/Al ratio of 3.1 to 2.4 suggesting the improvement of crystallinity. Further, the application of zeolite on the adsorption of the cationic dye Rhodamine 6G (R 6G) from aqueous solution in a batch process was investigated. Besides, the effect of parameters such as the effect of time, temperature, pH, dosage, agitation speed, kinetics, and isotherms on the removal of dyes was studied. The results indicate that adsorption of dye is more significant at pH = 6 indicating the zeolite surface is positively charged. The proficient sorption efficacy of R 6G onto ZSM-22 followed pseudo-second-order kinetic model and fits well with the Langmuir adsorption isotherm with maximum specific removal of 195.3 mg/g. Moreover, the possible adsorption mechanism for the selective separation of dye using CFA is mainly due to the electrostatic interactions and the hydrogen bonding. Finally, the key takeaways of the present research are that zeolite ZSM-22 is a prospective candidate as an adsorbent for the separation of dye molecules.