SYNTHESIS OF NOVEL CROWN ETHER INCORPORATING THE (−)-(5S,6R,13S,14R)-5,6,13,14-TETRAHYDRO-5,13-METHANOCYCLOOCTA[1,2-a:5,6-a′]DINAPHTHALENE-6,14-DIOL SUBUNIT AS THE C2-SYMMETRIC CHIRAL CENTER

Koichiro Naemura,Rinko Fukunaga

doi:10.1246/cl.1985.1651

SYNTHESIS OF NOVEL CROWN ETHER INCORPORATING THE (−)-(5S,6R,13S,14R)-5,6,13,14-TETRAHYDRO-5,13-METHANOCYCLOOCTA[1,2-a:5,6-a′]DINAPHTHALENE-6,14-DIOL SUBUNIT AS THE C2-SYMMETRIC CHIRAL CENTER

Koichiro Naemura, Rinko Fukunaga

https://doi.org/10.1246/cl.1985.1651

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Journal: Chemistry Letters	Publication Date: Nov 5, 1985
Citations: 20

Affiliation: Osaka University

#Chiral Recognition Property #Source Of Chirality + Show 7 more

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Abstract

Abstract (−)-5,6,13,14-Tetrahydro-5,13-methanocycloocta[1,2-a:5,6-a′]dinaphthalene-6,14-diol was synthesized and its absolute configuration was established. Optically active crown ether was prepared by using this glycol as a source of chirality and its chiral recognition property was examined.

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