Abstract
The reaction of the lanthanide oxides, bromotrimethylsilane and water in THF resulted in [LnBr3(THF)x]. If digylme (diglyme = diethylen glicol dimethyl ether) was added to these reaction mixtures in the mole ratio n(Ln): n(diglyme) ∼ 1: 2.2 – 3, the ionic complexes [LnBr2(diglyme)2][LnBr4(diglyme)] (Ln = La (1), Sm (2), Eu (3)) were isolated. Crystal structures of the two new complexes, 2 and 3, which were recrystallized from dichloromethane, were determined. The immediate reaction of the complexes 1 and 2 with HMPA (HMPA = hexamethylphosphoramide) in toluene resulted in [LnBr2(HMPA)4]Br·0.5H2O (Ln = La(4), Sm (5)).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
