Abstract
The reaction of meso-tetraarylporphyrins (H 2tap) with phosphorus(III) chloride has been studied in the solid state. The reaction products are intermediate sitting-atop (i-SAT) complexes in which two pyrrolenine nitrogen atoms of the porphyrins act as electron donors to the phosphorus(III) atoms and two protons on the pyrrole nitrogen atoms remain. These new complexes have been characterized by ( 1H, 31P, 13C) NMR, FT-IR and UV–Vis spectroscopy, elemental analysis and electrical conductometry.
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