Abstract
Treatment of iron complex (η5-C5H5)Fe(CO)2CH2CCPh 1 with nitrogen-containing 1,3-dipolar reagents (nitrile oxides and azomethine ylide) yields six-membered σ-heterocyclic iron complexes, due to cycloaddition and subsequent 1,2-migration of the (η5–C5H5)2Fe (CO) group.
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