Abstract
A series of novel heteroarylidene malonate derived bis(thiazoline) ligands 1 and 2 were synthesized and applied to a Friedel–Crafts reaction between indole and alkylidene malonate. The Cu(OTf) 2 complex of ligand 2b bearing a benzyl group afforded moderate to excellent enantioselectivity for the adducts (up to >99% ee).
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