Abstract
The Bu 3SnH - AIBN induced radical additions of 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl derivatives, bearing α-Br ( 1), α-I ( 5) β-OCSSMe ( 7), and β-SePh ( 8) groups on the anomeric carbon, with olefins such as dimethyl maleate, methyl vinyl ketone, dimethyl acetylenedicarboxylate, butyl vinyl ether, and N -ethylmaleimide were examined for a synthesis of C -glycosyl compounds.
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