Abstract
The propargylsilane dihydropyridinones, prepared in a ytterbium(III) triflate-catalyzed three-component reaction involving an aza-Diels-Alder reaction with Danishefsky’s diene, undergoes a fluoride-induced intramolecular Michael addition to afford allenidene indolizidinones in good to excellent yields as single diastereomers. The stereochemistry was established by NMR and X-ray crystal structure analysis. An extension to the preparation of analogous aza[4.4.0]bicyclic systems is also reported.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
