Abstract
Di- and triblock copolymers of styrene and butyl acrylate with controlled molar masses (Mn up to ≈ 105) were sequentially prepared by radical atom transfer polymerization in a homogeneous medium using chlorine end capped polymers as initiators and the copper(I) chloride/bipyridine complex as catalyst, in the presence of dimethylformamide. Random poly(styrene-co-butyl acrylate) was synthesized and the cross-over reactions between Cl end capped polystyrene and poly(butyl acrylate) to the opposite monomers were examined.
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