Abstract
The new organic–inorganic hybrid material (C6H7N2S)2[SbCl4]Cl was synthesized by slow evaporation method and characterized by single-crystal X-ray diffraction, infrared absorption, Hirshfeld surface analysis, optical absorption and photoluminescence measurements. The Centro symmetric compound crystallizes in the triclinic system of space group {text{P}}bar{1} with two formula units cell (Z = 2).The crystal structure is composed of a discrete [SbCl4]− anion and two isolated chloride Cl− anions which carried the same negative charge to balance the total charge of this compound surrounded by the 4 pyridiniumethioamide cations. Organic and inorganic parts which are linked by means of hydrogen bonding contacts N–H···Cl with N···Cl length are varied in the range of 3.221–3.456 Å to form a Zero-dimensional network. The infrared study performed at room temperature charge in the 4000–400 cm−1 frequency regions confirms the existence of the organic cation [C6H7N2S]+ and that of the [SbCl4]− anion. The Photoluminescence spectrum exhibits a broad and strong band of luminescence located at 1.95 eV (635 nm), which can be even observed with the naked eye at room temperature and is due to exaction emission. The various intermolecular interactions of the two independent cations and six chloride atoms were examined via Hirshfeld surface analysis.
Highlights
The group of halogenoantimonates (III) and halogenobismuthates (III) organic–inorganic hybrids are interesting systems because of the opportunity to associate the organic and the inorganic materials properties.the coordination compounds of the main group metals which are characterized by their ns2 electronic lone pair at the metal, present a large variety of differentElectronic supplementary material The online version of this article contains supplementary material, which is available to authorized users.1 3 Vol.:(0123456789)Journal of Inorganic and Organometallic Polymers and Materials (2020) 30:889–898 naturally isolated molecules (0D) [6, 7], infinite chains (1D) [8] or two dimensional (2D) networks
Based on recent research works on organic–inorganic metal halides compounds taken as a support to study the effects of the size and the coordination mode of the cation, we have successfully synthesized a new Zero-dimensional organic–inorganic hybrid compound of the formula (C5H7N2S)2[SbCl4]Cl
The results of single-crystal X-ray diffraction analysis at room temperature reveal that the title compound crystallizes in the centrosymmetric triclinic P1̄ space group
Summary
The group of halogenoantimonates (III) and halogenobismuthates (III) organic–inorganic hybrids are interesting systems because of the opportunity to associate the organic and the inorganic materials properties. More than 30 various anionic structures have been isolated so far [9, 10] In these materials, the crystal packing is defined by the interaction between the two organic and inorganic entities, which can be hydrogen bonds, van der Waals, or electrostatic interactions. Based on recent research works on organic–inorganic metal halides compounds taken as a support to study the effects of the size and the coordination mode of the cation, we have successfully synthesized a new Zero-dimensional organic–inorganic hybrid compound of the formula (C5H7N2S)2[SbCl4]Cl. This research work reports the chemical synthesis, structure characterization by X-ray diffraction, infrared spectroscopy (IR), and optical (photoluminescence and absorption) properties of the 4 pyridiniumethioamide chloride tetrachloro antimonates (III)
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
