Abstract
Abstract An optically active dimanganese(III) complex was synthesized by a template reaction of 5,5′-(9,9-dimethylxanthene-4,5-diyl)bis(salicylaldehyde), (1R,2R)-1,2-cyclohexanediamine, and MnCl2, in which two manganese(III) Schiff-base units are cofacially arranged by two 9,9-dimethylxanthenediyl spacers. The dimanganese complex catalyzed the asymmetric oxidation of methyl phenyl sulfide by iodosobenzene.
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