Abstract
Fluorinated heterocycles have been promising in the field of medicinal, agrochemical and materials chemistry due to their unique properties. However, despite the potentially very useful structures of fluorinated isocoumarins, the synthetic method of fluorinated isocoumarins remains a challenging topic. Herein, we describe the synthetic method of fluorinated isocoumarins by tandem coupling-cyclization-deacylation reaction of readily available 2-halobenzoic acids and 2-fluoro-1,3-diketones. This study provides one of the few synthetic methods of fluorinated isocoumarins.
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