Abstract
Abstract Two double helical compounds with a general cationic structure [MII2(L1)2(Cl)3]+ have been obtained by treatment of L1 (L1 = 2-pyridyl methyl ketazine) and hydrated MIICl2 in MeOH, which were isolated as a PF6- salt (M Ni, 1) and a ClO4− salt (M Mn, 2), respectively. They represent first examples of double helicates of diazine complexes containing pseudo octahedral-coordinated metal ions. Their crystal structures have been determined by X-ray crystallography and the corresponding magnetic properties have been investigated in detail.
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