Abstract
AbstractA copper cyanide coordination polymer [Cu8(CN)8(bbtz)2]n (1) [bbtz = 1,4‐bis(1,2,4‐trizal‐1‐ylmethyl)benzene] was synthesized following a synchronous redox and self‐assembly reaction under the solvothermal condition, and characterized by elemental analysis, infrared spectroscopy, and single‐crystal X‐ray diffraction. Interestingly, complex 1 exhibits a two‐dimensional conjugated pillared double‐layer architecture and an unprecedented (3,3,4)‐connected network with the point symbol (6.7.10)2(6.72)2(62.73.10) topology. Moreover, the thermogravimetric analysis indicates complex 1 has highly thermal stability, and the solid‐state emission spectrum for its crystalline material displays a strong green luminescence band (λmax = 565 nm) at room temperature. The electrochemical behavior of complex 1 is determined by the scan rates in the range from –0.5 to +0.3 V at room temperature, and exhibits different redox processes.
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