Abstract
Here we report two Ba(II) coordination compounds, 2D [Ba(btzphda)(H2O)4] (1) and 3D [Ba2(pytzipa)4(H2O)3]·2H2O (2) derived from 1,3-bis(tetrazol-5-yl)benzene-N2,N2′-diacetic acid (H2btzphda) and 5-(4-pyridyl)tetrazole-2-isopropionic acid (Hpytzipa). Furthermore, differential scanning calorimetry (DSC) and thermogravimetric-differential thermogravimetric (TG-DTG) analyses were applied to evaluate the thermal decomposition behavior of such compounds. The relevant thermodynamic parameters (ΔH, ΔS, and ΔG) of the decomposition process of compounds 1 and 2 were calculated, as well.
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