Abstract
Reacting cadmium(II) perchlorate with the ammonium salt of diphenyldithiophosphinic acid in ethanol yielded the title compound, which crystallized in the triclinic space group P 1 with a = 9.273(1), b = 10.426(1), c = 13.845(3) Å, α = 94.38(1), β = 103.16(1), γ = 104.63(1)° and Z = 2. The crystal contains dimeric complexes in which two cadmium atoms and two bridging ligands form an eight-membered ring, the coordination of each metallic centre being made up to four by an additional S,S-dentate chelating diphenyldithiophosphinate ligand. Solid state vibrational spectra (IR and Raman) and multinuclear NMR spectra in DMSO solution ( 13C, 31P and 113Cd) are discussed and compared with those of aliphatic cadmium(II) dithiophosphinates.
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