Abstract
AbstractThe first two‐dimensional lanthanum(III) coordination polymer, [La(1,5‐NDS)1.5(H2O)5]n (1) (1,5‐NDS2− = 1,5‐naphthalenedisulfonate), was synthesized and structurally characterized by single‐crystal X‐ray diffraction analysis. The disulfonate ligands act in the η1:η1:μ2 and η1:η1:η1:μ3 binding modes to link the LaO9 tricapped trigonal prisms into a lamellar structure. It exhibits strong purple emission in the solid state.
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