Abstract
A new cadmium(II) coordination polymer with 3,4-thiophe- nedicarboxylic acid (H2tdc) and 1,2-bis(4-pyridyl)ethane (bpa) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Compound {[Cd(tdc)(bpa)(H2O)]·2H2O}n (1), is monoclinic, space group C2/c with a = 19.222(9), b = 16.433(8), c = 13.168(6) Å, β = 96.429(2)°, V = 4133 (3) Å3, Z = 8, Mr = 520.82, Dc = 1.674 g/cm3, F(000) = 2096, and μ = 1.20 cm−1. The final refinement gave R = 0.0250 and wR = 0.0657 for 3325 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the title compound exhibits a 4-connected three-dimensional framework with irl topology. Furthermore, the luminescent property of 1 is investigated, which demonstrates that the title compound may be a good candidate as a photoactive material.
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