Abstract
Two new transition metal-based coordination polymers, [Cu(fdc)(dmbpy)(H2O)]n (1) {[Ni2(fdc)2(bipy)2(H2O)4]·(H2O)2}n (2) (fdca = 2,5-furandicarboxylic acid, dmbpy = 3,3′-dimethyl-4,4′-bipyridine, bipy = 4,4′-bipyridine) have been synthesized under the same reaction conditions (H2O, pH 7–8, and 130 °C) and were structurally characterized. 1 is a ladder chain, whereas 2 shows a 2D (4,4) network. Both 1 and 2 are further connected into 3D structures through hydrogen bonds. Furthermore, the magnetic properties of 1 and 2 are also investigated.
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