Synthesis and x-ray structure of the first lanthanide 2-mercaptopyridine n-oxide complex, tris-(1-hydroxy-2(1H)-pyridinethionato-o, s) bis [sulfinylbis (methane)] samarium(III)

Ren-Gen Xiong,Jing-Lin Zuo,Xiao-Zeng You

doi:10.1016/0277-5387(96)00030-7

Synthesis and x-ray structure of the first lanthanide 2-mercaptopyridine n-oxide complex, tris-(1-hydroxy-2(1H)-pyridinethionato-o, s) bis [sulfinylbis (methane)] samarium(III)

Ren-Gen Xiong, Jing-Lin Zuo + Show 1 more

https://doi.org/10.1016/0277-5387(96)00030-7

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Journal: Polyhedron	Publication Date: Jun 1, 1996
Citations: 11

Affiliation: Nanjing University

#Reaction Of Sm #Dimethyl Sulfoxide + Show 8 more

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Abstract

The first crystallographically characterized 2-mercaptopyridine N-oxide (HPT) complex of samarium was obtained by the reaction of Sm(OAc)3 with NaPT in dimethyl sulfoxide (DMSO). The 2-mercaptopyridine N-oxide ligand generates an eight-coordinate complex, Sm(PT)3(DMSO)2, in which the solvent molecules, DMSO, take part in coordination to Sm. The Sm atom has a distorted dodecahedron with the Sm-S and Sm-O bond distances of 2.878(2)-2.916(2) and 2.359(5)-2.440(4) A, respectively. Copyright © 1996 Elsevier Science Ltd

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