Abstract

A novel heterometallic complex with three different metals, the linear complex [(CH 3CH 2) 4N][(PPh 3) 2{AgS 2WS 2Cu}(CN)] ( I), has been obtained from the reaction of [Et 4N] 2[WS 4Cu(CN)] with (PPh 3 2AgNO 3. In the new complex the three different metals are almost colinear with the CN − ligand and the S 2WS 2CuCN moiety from the anionic reactant is retained in the structure.

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