Abstract

Polyaniline (PANI) is synthesized in the presence of montmorillonite (Mt). Mt has small spaces between its layers. This interlayer spacing functions as a reaction field for the production of PANI with an organized structure. Mt/PANI composites thus synthesized were characterized by the IR and the UV-Vis optical absorption spectroscopy measurements. Scanning electron microscopy observation showed that the PANI is covered by the flake structure of the Mt. A cylindrical structure was also observed in the sample. X-ray diffraction analysis indicated that the composite of the PANI and the Mt had an ordered structure, suggesting that the macroscopic structure of the natural clays can provide a unique reaction field for polymerization reactions.

Highlights

  • Researchers have recently employed microporous materials to create reaction fields [1,2]

  • This study suggests that small spaces in materials can effectively function as reaction fields

  • We recently engaged in liquid crystal (LC) polymerization

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Summary

Introduction

Researchers have recently employed microporous materials to create reaction fields [1,2]. This study suggests that small spaces in materials can effectively function as reaction fields. We carry out polymerization in the presence of montmorillonite (Mt) with a layer structure as a micro-reaction field. PANI composites can be prepared in the presence of metals, minerals, and organics [3,4]. Studies on conducting polymer/inorganic layer clay have been conducted [5,6]. Polymerization can be carried out between the layers of Mt, which act as reaction fields [9,10]. We carry out the polymerization of aniline in the presence of Mt as an inorganic reaction field for the production of organized polymers

Materials
Instruments
UV-Vis Absorption Spectra
Conductivity
Electron Spin Resonance
SEM Observation
X-Ray Diffraction

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