Abstract
AbstractSalts of protonated sulfur dioxide were synthesized by recrystallization of [FS(OX)2][SbF6] (X=H, D) in aprotic solvents at low temperatures. Hemiprotonated sulfur dioxide [(SO2)2H][Sb2F11] was obtained from the solvent SO2 and the monoprotonated sulfur dioxide [OSOD][Sb2F11], using 1,1,1,2‐tetrafluoroethane as solvent. For both compounds, single crystals were obtained and an X‐ray structure analysis was conducted. Furthermore, the salts were characterized by Raman spectroscopy and the results were discussed together with quantum chemical calculations on the M06‐2X/aug‐cc‐pVTZ level of theory.
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