Abstract
A new hybrid vanadium arsenate [VO2(phen)]2(H2AsO4)⋅H3O 1 (phen = 1,10′-phenanthroline) was synthesized under hydrothermal reaction conditions and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR and elemental analyses. Crystal data for 1: monoclinic, P21/n, a = 9.175(2) A, b = 18.638(5) A, c = 14.482(4) A, β = 102.333(3)∘, V = 2419(1) A3, Z = 4. Compound 1 is composed of discrete tricyclic (VO2)2(H2AsO4) cluster decorated with two phen ligands. The discrete arsenic–vanadium clusters are extended into three-dimensional supramolecular arrays via π–π stacking interactions of phen groups.
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