Abstract
An efficient method was developed for the preparation of three tetraorganodistannoxane complexes, (C2H5)8Sn4Cl2(CH3O)2O2 (1), (CH3)8Sn4(C3H4N3S)2(CH3O)2O2 (2) and (C4H9)8Sn4(C3H4N3S)2(CH3O)2O2 (3). All prepared complexes were characterized by infrared, 1H, 13C and 119Sn NMR spectroscopes and elemental analysis. The molecular structure of a representative complex (1) was determined by single-crystal X-ray diffraction. Results showed that 1 is a tetranuclear, centrosymmetric dimeric, and contains two endo-cyclic five-coordinated tin atoms and two exo-cyclic five-coordinated tin atoms. Compound 1 lies about a center of inversion and the tetranuclear molecule features a three-ring-staircase Sn4O4 core. The asymmetric unit of 1 contains two independent Sn(IV) atoms and a 2D infinite rigid chain structure forms via C–H···Cl interactions between tetranuclear units.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
