Abstract
Abstract Two new Hofmann-type complexes, M (1,3-thiazolidine-2-thione)2 Ni(CN)4 (where M = Ni and Cd), were synthesized and characterized by elemental analysis, magnetic susceptibility data, IR and Raman Spectroscopy. Their structure consist of planar infinite polymeric layers of {M-NI(CN)4}∞. 1,3-thiazolidine-2-thione coordinated to M atom above and below this layers is monodentate and S-bonded in these complexes.
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