Abstract
A versatile synthetic route to conjugated bimetallic ruthenium complexes with σ,σ-bridging azobenzene chains was developed, and new ruthenium complexes with various ligands were synthesized and characterized. These bimetallic complexes showed a remarkable absorption in the visible region ( λ max: 452–483 nm), and undergo trans-to- cis isomerization under UV light irradiation for short time. Electrochemical study showed that the metal centers in bimetallic complexes containing the CH CH C 6H 4N NC 6H 4 CH CH bridge interact with each other.
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