Abstract
Allyloxy-based biphenyl liquid crystals, composed of alkyl chain, trans-cyclohexane and biphenyl mesogenic cores, ethylene linking groups, lateral fluoro substituents and allyloxy terminal groups were prepared via a six-step reaction based on 4-alkylcyclohexanecarbonitrile. Their structures were confirmed via infrared spectrometry, mass spectra and nuclear magnetic resonance. The mesomorphic properties of the present compounds were investigated by differential scanning calorimetry and polarising optical microscopy. The compounds exhibited negative dielectric anisotropy from −3.36 to −4.29 and a broad nematic mesophase with low melting points and high clearing points. The effects of the allyloxy terminal group and the lateral fluoro substituents on the mesomorphic properties and negative dielectric anisotropies are discussed. The present allyloxy-based biphenyl liquid crystals have potential for use in liquid crystal display mixtures.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.