Abstract
The addition reaction of triorganosilanes to 1-(5-methylhexene-5-yn-2-yloxy)-2,3-epoxypropane in the presence of H2PtCl6.6H2O catalyst proceeds via a triple bond, but with an advantageous yield (75-85%) of the β-isomer (relative to the oxygen atom). The addition of dimethylamine to the epoxy ring leads to secondary amino alcohols, and the corresponding episulfide is obtained by the reaction of epoxysilane with thiocarbamide. Epoxy-1,4-dienes can be used as modifiers for phenol-formaldehyde resin
Highlights
IntroductionSilanes having the Si–H bond are extremely easy to attach to various unsaturated hydrocarbons and other organic and organic elemental compounds with double and triple bonds [1]
Silanes having the Si–H bond are extremely easy to attach to various unsaturated hydrocarbons and other organic and organic elemental compounds with double and triple bonds [1].Even though the hydrosilylation method has been used for about 60 years, interest in it has not waned to this day
The study has shown that the hydrosilylation of the indicated epoxyenin proceeds via a triple bond, but with the formation of βand γ-isomers, with a predominance of β-product (Figure 1) [3]
Summary
Silanes having the Si–H bond are extremely easy to attach to various unsaturated hydrocarbons and other organic and organic elemental compounds with double and triple bonds [1]. Even though the hydrosilylation method has been used for about 60 years, interest in it has not waned to this day. This was previously caused by its universality since a silyl group with the desired function can be attached to almost any unsaturated compound. The study has shown that the hydrosilylation of the indicated epoxyenin proceeds via a triple bond, but with the formation of βand γ-isomers (relative to the oxygen atom), with a predominance of β-product (Figure 1) [3]
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
