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Abstract
AbstractBy reacting poly(methacryloyl chloride) (PMKC) with allyl amine, a multiallyl monomer in PMKC matrix has been obtained. Free‐radical polymerization of multiallyl monomer in diluted solutions at a concentration of 12 g/L multiallyl monomer occurs partly along ordered allyl units in the matrix and results in ladder‐type branched polymers. The polymers obtained are soluble in alcohols, DMF, DMSO and have unreacted allyl double bonds. The structures of multiallyl monomer and homopolymer have been found on the basis of elemental analysis, IR and 1H‐NMR spectra and an examination of the products of hydrolysis. The effect of the reaction of degradative chain transfer on the structure of the polymer obtained has been discussed.
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Schedule a callMore From: Journal of Polymer Science Part A: Polymer Chemistry
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