Synthesis and photoluminescence study of Dy3+ activated SrAl12O19 phosphor

Abstract

Dy3+ doped SrAl12O19 phosphors, capable of radiating white light, were successfully synthesized via combustion method. Phase identification, morphological observations and elemental examination were done by employing X-ray diffraction, Field emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS). The peaks in the X-ray diffraction patterns are found to be indexed well with the hexagonal phase (JCPDS card number 80-1195). Under 350 nm of excitation wavelength, the PL emission bands were peaking at 478 nm and 573 nm, which can be ascribed to the intra-4f transition of Dy3+. The emission data were analyzed for determining the CIE chromaticity coordinates and the correlated color temperature (CCT). A cool white light with chromaticity coordinates x = 0.3098 and y = 0.3538 and correlated color temperature of 6542 K was achieved for 3 mol% at 350 nm excitation. These results indicate that SrAl12O19:Dy3+ have practical applications in UV-pumped white light emitting diodes.