Abstract
Hydroboration polymerization of low molecular weight allyl-telechelic polyisobutylene with narrow molecular weight distribution gave a novel stable organoboron segmented block copolymer by using tripylborane as a boron monomer. The chain transformation reaction of the copolymer was also examined. The reaction with α,α-dichloromethyl methyl ether (DCME) gave the corresponding poly-isobutylene segmented poly(alcohol).
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